New nylon 6.6 recycling process

22/05/2025
Japanese group Toray Industries has announced having successfully depolymerised polyamide 6.6 using subcritical water that works in minutes and recovers the materials two monomer building blocks. Subcritical water, it said, is water in a state of high temperature and high pressure, and in this form dissolves and hydrolyses organic compounds.

The company drew on its prior experience in the chemical recycling of nylon 6 (to retrieve caprolactam) to develop this new method. The company said it had developed a proprietary technology to suppress side reactions, making it possible to efficiently recover high yields of hexamethylenediamine and adipic acid monomers, used to make nylon 6.6. It believes this method can halve carbon dioxide emissions of polyamide 6.6 production compared with petroleum-based sources.

Demand for nylon 66 is estimated at 100,000 tonnes annually in Japan and 1.3 million tonnes worldwide. Due to its resistance to heat and tearing, it is used to make airbags and tyre cords. Toray said that stricter recycling regulations for automotive and other plastics in Japan have made it mandatory to collect used nylon 6.6-based airbags, making it a promising source of feedstock for the company’s new technology.

This year, Toray said it will be assessing the technology and evaluating its efficiency with customers, before the possible launch of mass production in around 2030, when new thresholds for plastic recycling regulations are expected to come into force.